Kinetic isotope effects in oxidation reaction of C2H4 and C2D4 by p-benzoquinone in the Pd2+—HClO4—CH3CN—H2O system
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DOI: 10.1007/s11172-017-1830-8
Abstract: AbstractKinetic isotope effects (KIE) have been measured for oxidation reactions of ethylene by p-benzoquinone in Pd2+—MeCN—H2O—HClO4 system. Under the conditions of preferred formation of complex Pd(MeCN)(H2O)32+ the ratio between the initial reaction rates $$R_{{C_2}{H_4}} 0/R_{{C_2}{D_4}}… read more here.
Keywords: isotope effects; c2h4 c2d4; h2o; benzoquinone pd2 ... See more keywords