Palladium-Catalyzed Dearomatization of Benzothiophenes: Isolation and Functionalization of a Discrete Dearomatized Intermediate
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DOI: 10.1055/a-2092-9012
Abstract: A Pd-catalyzed decarboxylative dearomatization reaction of of a heterocyclic substrate enables access to an uncommon reaction intermediate, that rearomatizes in the presence of amine bases in a net C–H functionalization sequence. The dearomatized benzo[b]thiophene intermediate… read more here.
Keywords: functionalization; dearomatization; palladium catalyzed; benzothiophenes isolation ... See more keywords