Probing through-space and through-bond magnetic exchange couplings in a new benzotriazinyl radical and its metal complexes.
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DOI: 10.1039/c9dt01918a
Abstract: The synthesis and characterization of a new chelating benzotriazinyl radical (Rad2) are described. Crystallographic studies coupled with SQUID magnetometry on Rad2 reveal the presence of discrete radical pairs which are antiferromagnetically coupled. The reaction of… read more here.
Keywords: exchange; metal; metal complexes; benzotriazinyl radical ... See more keywords