Curing kinetics, thermal, and adhesive properties of acetylene-terminated benzoxazine
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Applied Polymer Science"
DOI: 10.1002/app.44547
Abstract: The acetylene-terminated benzoxazine monomer (BB-apa) has been synthesized using 2,2-bis(4-hydroxyphenyl)butane, 3-aminophenylacetylene, and paraformaldehyde. The structure of the monomer was characterized by FTIR spectroscopy and 1H NMR spectra, which indicated that the reactive oxazine ring and… read more here.
Keywords: curing kinetics; polymerization; terminated benzoxazine; benzoxazine ... See more keywords
2,2,6,6-Tetramethylpiperydinyl-1-oxyl (TEMPO) Functionalized Benzoxazines Prepared with a One-Pot Synthesis for Reactive/Crosslinkable Initiators of Nitroxide Mediated Polymerization.
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201700078
Abstract: In this work, the incorporation of a 2,2,6,6-tetramethylpiperydinyl-1-oxyl (TEMPO) group to a benzoxazine ring is performed using a one-pot synthesis for the preparation of TEMPO-functionalized benzoxazine compounds and polymers as reactive and crosslinkable initiators for… read more here.
Keywords: polymerization; tetramethylpiperydinyl oxyl; benzoxazine; oxyl tempo ... See more keywords
Investigation of polycyanurate/benzoxazine curing system
Sign Up to like & getrecommendations! Published in 2018 at "Microsystem Technologies"
DOI: 10.1007/s00542-017-3347-3
Abstract: Abstract In this study, we investigated the curing system between polycyanurate and benzoxazine derivatives which could be a useful system for producing low-k thermoset materials. This curing reaction contains the following steps: (1) the ring-opening… read more here.
Keywords: polycyanurate benzoxazine; system; benzoxazine; reaction ... See more keywords
Synthesis, polymerization kinetics and thermal properties of para-methylol functional benzoxazine
Sign Up to like & getrecommendations! Published in 2018 at "Reactive and Functional Polymers"
DOI: 10.1016/j.reactfunctpolym.2017.06.017
Abstract: Abstract Monofunctional benzoxazine with para -methylol functionality has been synthesized via Mannich condensation. The chemical structure of the synthesized monomer is confirmed by 1 H nuclear magnetic resonance (NMR), 13 C NMR and Fourier transform… read more here.
Keywords: benzoxazine; functional benzoxazine; para methylol; methylol functional ... See more keywords
Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b01297
Abstract: A systematic study has been carried out to develop a material with significant protection properties from galactic cosmic radiation and solar energetic particles. The research focused on the development of hydrogen-rich benzoxazines, which are particularly… read more here.
Keywords: benzoxazine; hydrogen rich; development hydrogen; radiation shielding ... See more keywords
An apigenin-based bio-benzoxazine with three polymerizable functionalities: sustainable synthesis, thermal latent polymerization, and excellent thermal properties of its thermosets
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/d0py00983k
Abstract: Benzoxazine resins have been attracting continuous attention from both academia and industry owing to the property of molecular design flexibility and high performance of their thermoset polymers. However, a reduction in the polymerization temperature, a… read more here.
Keywords: apigenin based; polymerization; excellent thermal; benzoxazine ... See more keywords
Preparation and properties of silicon-containing benzoxazine with high thermal stability
Sign Up to like & getrecommendations! Published in 2022 at "High Performance Polymers"
DOI: 10.1177/09540083221083474
Abstract: A silicon-containing benzoxazine (PDpsp-a) was synthesized from bis(p-hydroxyphenyl)diphenylsilane, aniline, and paraformaldehyde. The structure of the monomer was supported by 1H-NMR and FTIR spectra. The curing behavior of benzoxazine was evaluated by differential scanning calorimetry and… read more here.
Keywords: thermal stability; benzoxazine; high thermal; silicon containing ... See more keywords
Mechanical and thermal properties of fully green composites from vanillin-based benzoxazine and silane surface modified chopped basalt fibers
Sign Up to like & getrecommendations! Published in 2022 at "High Performance Polymers"
DOI: 10.1177/09540083221143688
Abstract: By following the rules of green chemistry, a novel composite is developed from a renewable and ecofriendly resource, namely the vanillin. The latter was used as a phenolic precursor for the microwave synthesis of a… read more here.
Keywords: silane; based benzoxazine; surface; benzoxazine ... See more keywords
Green composites from vanillin-based benzoxazine and silane surface modified chopped carbon fibers
Sign Up to like & getrecommendations! Published in 2022 at "Polymers from Renewable Resources"
DOI: 10.1177/20412479221147052
Abstract: By following the rules of green chemistry, a novel composite is developed from a renewable and ecofriendly resource, namely, vanillin. The latter was used as a phenolic precursor for the microwave synthesis of a bio-based… read more here.
Keywords: benzoxazine; green composites; silane surface; based benzoxazine ... See more keywords
Adhesive Films Based on Benzoxazine Resins and the Photoreactive Epoxyacrylate Copolymer
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma15051839
Abstract: UV-cross-linkable and thermally curable self-adhesive structural tapes (SATs) were compounded using solid commercial benzoxazine resins (Araldite MT 35700 and Araldite MT 35910) and a photoreactive epoxyacrylate copolymer (EAC). As initiators of benzoxazine resin polymerization and… read more here.
Keywords: photoreactive epoxyacrylate; benzoxazine; cross; benzoxazine resins ... See more keywords
Synthesis and Characterization of Benzoxazine Resin Based on Furfurylamine
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma15238364
Abstract: This paper presents an investigation of the modification of natural oxazines to traditional bisphenol A benzoxazines. Eugenol was reacted with furfurylamine to synthesize a new type of benzoxazine (eugenol–furfurylamine benzoxazine), with a yield of 77.65%;… read more here.
Keywords: furfurylamine benzoxazine; synthesis characterization; benzoxazine; bisphenol ... See more keywords