Secondary phosphine oxide-triggered selective oxygenation of a benzyl ligand on palladium.
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DOI: 10.1039/d0cc05572g
Abstract: The oxygenation of a benzyl ligand in [PdBnCl(cod)] was dramatically accelerated by using secondary phosphine oxides (SPOs), selectively affording either BnOOH or BnOH, depending on the concentration of O2. The SPOs coordinate to palladium in… read more here.
Keywords: secondary phosphine; oxygenation benzyl; benzyl ligand;