Brønsted Acid Catalyzed Dehydroxylative Cyanation of Benzylic Alcohols with Trimethylsilyl Cyanide Using 1,1,1,3,3,3‐Hexafluoro‐2‐propanol as a Solvent
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DOI: 10.1002/ejoc.202400474
Abstract: A concise and direct cyanation of secondary and tertiary benzylic and allylic alcohols catalyzed by Brønsted acid has been developed using trimethylsilyl cyanide (TMSCN) as a cyanide source and 1,1,1,3,3,3‐hexafluoro‐2‐propanol (HFIP) as a solvent. The present… read more here.
Keywords: benzylic; cyanide; trimethylsilyl cyanide; cyanation ... See more keywords
HOO• as the Chain Carrier for the Autocatalytic Photooxidation of Benzylic Alcohols
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DOI: 10.3390/molecules29143429
Abstract: The oxidation of benzylic alcohols is an important transformation in modern organic synthesis. A plethora of photoredox protocols have been developed to achieve the aerobic oxidation of alcohols into carbonyls. Recently, several groups described that… read more here.
Keywords: benzylic; carrier autocatalytic; chain carrier; autocatalytic photooxidation ... See more keywords