Copper-catalyzed oxidative benzylic C(sp3)-H amination: direct synthesis of benzylic carbamates.
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DOI: 10.1039/d0cc05226d
Abstract: A new efficient strategy to access benzylic carbamates through C-H activation is reported. The use of a catalytic amount of a Cu(i)/diimine ligand in combination with NFSI ((PhSO2)2NF) or F-TEDA-PF6 as oxidants and H2NCO2R as… read more here.
Keywords: benzylic carbamates; oxidative benzylic; copper catalyzed; benzylic sp3 ... See more keywords