Iodine/DMSO promoted oxidation of benzylic Csp3–H bonds to diketones – A mechanistic investigation
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DOI: 10.1016/j.tet.2019.130617
Abstract: Abstract This article describes a mechanistic investigation into the I2/DMSO mediated benzylic Csp3–H oxidation of an α-methylene ketone. The electron paramagnetic resonance (EPR) spectrum centred at g = 2.0011 supports the involvement of iodine and benzylic radicals,… read more here.
Keywords: benzylic csp3; dmso; oxidation; mechanistic investigation ... See more keywords