Oxidative Fluoroarylation of Benzylidenecyclopropanes with HF·Py and Aryl Iodides via Iodonio-[3,3]-Rearrangement.
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DOI: 10.1021/acs.orglett.2c01150
Abstract: Reported herein is an in situ-generated hypervalent iodine-incorporating fluoroarylation of benzylidenecyclopropanes using commercially available HF·Py and aryl iodides as fluorine and aryl sources, respectively. The reaction proceeds via regioselective 1,2-fluoroiodination of a double bond followed… read more here.
Keywords: aryl iodides; fluoroarylation benzylidenecyclopropanes; iodonio rearrangement; benzylidenecyclopropanes aryl ... See more keywords