Mono- and polynuclear Ag(i) complexes of N-functionalized bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state structures and reactivity.
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DOI: 10.1039/c6dt04755f
Abstract: The reactivity of the N-functionalized DPPA-type ligands (Ph2P)2N(p-Z)C6H4 [Z = H (1a), SMe (1b), OMe (1c)] with AgBF4 was investigated and revealed an unexpected influence of the para substituent Z of the N-aryl ligand. In… read more here.
Keywords: solid state; dppa type; bf4; bf4 bf4 ... See more keywords
Formation of iron(iii)–thiolate metallocyclophane using a ferrocene-based bis-isocyanide
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DOI: 10.1039/d0nj03967e
Abstract: Two ferrocene–isocyanide ligands, 1-isocyanoferrocene (FcNC) and 1,1′-diisocyanoferrocene [Fc(NC)2], were observed to react with the redox active iron–thiolate core complexes [(CpFe)2(μ-SEt)2(CH3CN)2][BF4]2 (1[BF4]2) to form the respective ferrocenyl–isocyanide adducts, [(CpFe)2(μ-SEt)2(FcNC)2][BF4]2 (2[BF4]2) and [(CpFe)2(μ-SEt)2(Fc(NC)2)][BF4]2 (3[BF4]2). By using ESI-MS,… read more here.
Keywords: cpfe set; bf4; formation; bf4 bf4 ... See more keywords