Stepwise Bi-Bi Bond Formation: From a Bi-centered Radical to Bi4 Butterfly and Bi8 Cuneane-Type Clusters.
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DOI: 10.1021/acs.inorgchem.0c01657
Abstract: In contrast to their lighter homologues (P, As, Sb), the synthesis of polybismuthane clusters is still restricted to classical solid-state approaches. We herein report on systematic reduction reactions of different bismuth precursors with Ga(I) and… read more here.
Keywords: bi4; centered radical; formation; stepwise bond ... See more keywords