Synthesis, crystal structures and electrochemical properties of Co(II) and Mn(II) complexes with asymmetric bulky BIAN ligands
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.03.034
Abstract: Abstract Series of newly designed Co(II) and Mn(II) complexes supported by sterically encumbered asymmetric bis(imino)acenaphthene (BIAN) ligands were synthesized through the reaction of metal dichlorides with the corresponding ligands. The metal complexes were characterized by… read more here.
Keywords: electrochemical properties; bian ligands; structures electrochemical; crystal structures ... See more keywords
Bay-Region Functionalisation of Ar-BIAN Ligands and Their Use Within Highly Absorptive Cationic Iridium(III) Dyes
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DOI: 10.1038/s41598-017-14996-4
Abstract: We report the synthesis, UV-vis absorption, electrochemical characterisation, and DFT studies of five panchromatic, heteroleptic iridium complexes (four of which are new) supported by Ar-BIAN ligands. In particular, the synthesis of an ester-functionalised Ar-BIAN ligand… read more here.
Keywords: bian ligands; functionalisation bian; iridium; region functionalisation ... See more keywords
Ferrous complexes supported by sterically encumbered asymmetric bis(arylimino)acenaphthene (BIAN) ligands: synthesis, characterization and screening for catalytic hydrosilylation of carbonyl compounds
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DOI: 10.1039/c7ra01511a
Abstract: Six ferrous chloride complexes ((Ar-BIANX)FeCl2: Ar = 2,6-diisopropylphenyl (Dipp), X = F (1), Cl (2), Me (3); Ar = mesityl (Mes), X = F (4), Cl (5), Me (6)) supported by sterically bulky asymmetric bis(arylimino)acenaphthene… read more here.
Keywords: bian ligands; bis arylimino; arylimino acenaphthene; acenaphthene bian ... See more keywords
Molybdenum(ii) complexes with p-substituted BIAN ligands: synthesis, characterization, biological activity and computational study.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00469f
Abstract: New complexes [Mo(η3-C3H5)X(CO)2(4-Y-BIAN)] (4-Y-BIAN = bis(4-Y-phenyl)-acenaphthenequinonediimine), with X = Br and Y = H, Me, OMe, COOH and X = Cl, Y = OMe, as well as the cation with X = NCMe and Y… read more here.
Keywords: synthesis characterization; complexes substituted; molybdenum complexes; bian ligands ... See more keywords