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Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c02961
Abstract: Dearomative photocycloadditions are valuable chemical transformations, serving as an efficient platform to create three-dimensional molecular complexity. However, the photolability of the original addition product especially within the context of ortho cycloadditions often causes undesired consecutive…
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Keywords:
bicyclic aza;
selective dearomative;
aza arenes;
ortho selective ... See more keywords
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1
Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc04638a
Abstract: Methyl groups can have profound effects in drug discovery but the underlying mechanisms are diverse and incompletely understood. Here we report the stereospecific effect of a single, solvent-exposed methyl group in bicyclic [4.3.1] aza-amides, robustly…
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Keywords:
water;
aza amides;
group bicyclic;
methyl group ... See more keywords