Bifunctional iminophosphorane superbases: Potent organocatalysts for enantio- and diastereoselective Michael addition reactions
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron"
DOI: 10.1016/j.tet.2018.06.021
Abstract: Abstract Bifunctional iminophosphorane (BIMP) organocatalysts catalyze the enantio- and diastereoselective Michael additions of high pKa cyclic malonamate ester pro-nucleophiles to nitroalkenes with reactivity profiles of up to 3 orders of magnitude greater than tertiary amine… read more here.
Keywords: iminophosphorane superbases; enantio diastereoselective; bifunctional iminophosphorane; diastereoselective michael ... See more keywords
Bifunctional Iminophosphorane Superbase Catalysis: Applications in Organic Synthesis.
Sign Up to like & getrecommendations! Published in 2020 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.0c00369
Abstract: ConspectusTo improve the field of catalysis, there is a substantial and growing need for novel high-performance catalysts providing new reactivity. To date, however, the set of reactions that can be reliably performed to prepare chiral… read more here.
Keywords: iminophosphorane; bifunctional iminophosphorane; catalysis; catalyst ... See more keywords