A Bifunctional Iron Nanocomposite Catalyst for Efficient Oxidation of Alkenes to Ketones and 1,2-Diketones
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b05197
Abstract: We herein report the fabrication of a bifunctional iron nanocomposite catalyst, in which two catalytically active sites of Fe–Nx and Fe phosphate, as oxidation and Lewis acid sites, were simultaneo... read more here.
Keywords: nanocomposite catalyst; bifunctional iron; iron nanocomposite; oxidation ... See more keywords
Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping
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DOI: 10.1038/s41467-024-53021-x
Abstract: The challenging synthesis of thermodynamic-unfavored cis-olefins through catalytic cross-coupling reactions requires the synergistic interaction of substrate-activating units and configuration-regulating catalysts. Successfully hitting these two birds with one stone, we herein develop a convenient photoredox access… read more here.
Keywords: catalyzed alkyne; tandem; bifunctional iron; alkyne selective ... See more keywords
Bifunctional iron-mediated multicomponent Markovnikov-selective radical hydrothiolation of alkenes
Sign Up to like & getrecommendations! Published in 2025 at "Organic Chemistry Frontiers"
DOI: 10.1039/d5qo00308c
Abstract: A bifunctional iron-mediated multicomponent reaction for Markovnikov-selective hydrothiolation of alkenes has been established. The reaction involves an iron-mediated hydrogen atom transfer and a single electron transfer process. read more here.
Keywords: mediated multicomponent; bifunctional iron; markovnikov selective; hydrothiolation alkenes ... See more keywords