Synthesis of Chiral Bifunctional NHC Ligands and Survey of Their Utilities in Asymmetric Gold Catalysis.
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DOI: 10.1021/acs.organomet.9b00400
Abstract: The synthesis and characterization of the chiral bifunctional NHC ligands based on the imidazo[1,5-a]pyridine (ImPy) scaffold are described. These ligands possess a fluxional biaryl axis and a chiral center. The configurational stability of the biaryl… read more here.
Keywords: bifunctional nhc; chiral bifunctional; gold catalysis; nhc ligands ... See more keywords