Synthesis and characterization of a bimetallic americium(III) pyrithionate coordination complex.
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DOI: 10.1039/d2cc03352f
Abstract: The aqueous reaction of sodium pyrithione, (Na)mpo, with 243AmCl3·nH2O yields a dimerized complex, [243Am(mpo)2(μ-O-mpo)(H2O)]2·3H2O. This compound is compared with isostructural lanthanide pyrithionates, where dimerization across the 4f-block is observed to be dependent upon the size… read more here.
Keywords: americium iii; iii; mpo; bimetallic americium ... See more keywords