Synthesis, characterization, ab initio quantum chemical calculations and molecular docking studies of Se bearing phenoxo-bridged bimetallic Ni(II) complexes
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.128771
Abstract: Abstract In this paper, we report the reactivity of Ni(dppe)Cl2; dppe = bis(diphenylphosphino)ethane, with phenol based selenium bearing macroacyclic Schiff bases, 2,6-bis({N-[2-(phenylselenato)ethyl]} benzimidoyl)-4-methylphenol and 2,6-bis({N-[3-(phenylselenato)propyl]}benzimidoyl)-4-methylphenol. The reaction of Ni(dppe)Cl2 with these Se2N2O ligands in 1:1 M ratio yield… read more here.
Keywords: quantum chemical; chemical calculations; bis; bimetallic complexes ... See more keywords
Synthesis of bimetallic complexes bridged by 2,6-bis(benzimidazol-2-yl) pyridine derivatives and their catalytic properties in transfer hydrogenation.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03178a
Abstract: A series of binuclear rhodium(i) and iridium(i) complexes with 2,6-bis(benzimidazol-2-yl) pyridine (bzimpy) derivatives were synthesized and characterized by elemental analysis and spectroscopic methods. The molecular and crystal structures of complex 3d were determined by the… read more here.
Keywords: transfer hydrogenation; bis benzimidazol; bimetallic complexes; benzimidazol pyridine ... See more keywords
Thiosemicarbazone(s)-anchored water soluble mono- and bimetallic Cu(ii) complexes: enzyme-like activities, biomolecular interactions, anticancer property and real-time live cytotoxicity.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt01309a
Abstract: The reactions of CuCl2·2H2O with chromone thiosemicarbazone ligands containing a -H or -CH3 substituent on terminal N yielded monometallic Cu(ii) complexes [Cu(HL1)Cl2] (1) and [Cu(HL2)Cl2] (2), whereas bimetallic Cu(ii) complexes [Cu(μ-Cl)(HL3)]2Cl2 (3), [Cu(μ-Cl)(HL4)]2Cl2 (4) and… read more here.
Keywords: time live; real time; bimetallic complexes; biomolecular interactions ... See more keywords
Mechanochromic luminescent materials of bimetallic Cu(i) complexes showing thermally activated delayed fluorescence
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Materials Chemistry C"
DOI: 10.1039/d0tc04607h
Abstract: Reversible mechanochromism is related to the breaking and restoring of hydrogen-bonding and luminescence color is tunable via the substituent. read more here.
Keywords: showing thermally; complexes showing; luminescent materials; mechanochromic luminescent ... See more keywords
Janus-type homo-, hetero- and mixed valence-bimetallic complexes with one metal encapsulated in a cyclodextrin.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00219a
Abstract: Bis-azolium salts with one azolium capping a perbenzylated α-cyclodextrin have been designed to generate Janus-type bimetallic complexes with various combinations of copper, silver, gold or palladium salts. Encapsulation of one metal center inside the cavity… read more here.
Keywords: janus type; one metal; bimetallic complexes;
Chiral bisoxazoline ligands designed to stabilize bimetallic complexes
Sign Up to like & getrecommendations! Published in 2018 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.14.175
Abstract: Chiral bisoxazoline ligands containing naphthyridine, pyridazine, pyrazole, and phenol bridging units were prepared and shown to form bimetallic complexes with various metal salts. X-ray crystal structures of bis-nickel naphthyridine-bridged, bis-zinc pyridazine-bridged, and bis-nickel as well… read more here.
Keywords: ligands designed; bisoxazoline ligands; designed stabilize; bimetallic complexes ... See more keywords