Hetero-Bimetallic Effect as a Route to Access Multinuclear Complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01466
Abstract: We report the synthesis of a key mononuclear intermediate complex based on a quinoid ligand and its further metalation to afford the corresponding hetero-bimetallic compound that revealed unique properties. An unprecedented hetero-bimetallic effect in coordination… read more here.
Keywords: bimetallic effect; chemistry; hetero bimetallic; ligand ... See more keywords
The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03571e
Abstract: Au@RhPd ultrathin nanowires are designed as a highly reactive and selective catalyst for the hydrogenation of phenol under ambient conditions. Au NWs modulate the electronic state of Rh atoms to enhance the adsorption of phenol… read more here.
Keywords: bimetallic effect; hydrogenation; hydrogenation phenol; effect promotes ... See more keywords