Bimetallic hexanuclear clusters in Ce/Zr-UiO-66 MOFs: in situ FTIR spectroscopy and modelling insights.
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DOI: 10.1039/d0dt01023e
Abstract: In situ FTIR spectroscopy in combination with results from DFT calculations was used to determine the composition of mixed-metal clusters {CexZr6-x(μ3-O)4(μ3-OH)4} in Ce/Zr-UiO-66 compounds. Detailed, quantitative evaluation of vibrational bands ν(OH) of (μ3-OH)CexZr3-x groups allowed… read more here.
Keywords: situ ftir; ftir spectroscopy; bimetallic hexanuclear; spectroscopy ... See more keywords