Photoinduced Copper‐Catalyzed Cross‐Coupling of Acylsilanes with Heteroarenes via Bimetallic Relay
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DOI: 10.1002/advs.202409457
Abstract: The transition metal‐catalyzed direct coupling reactions involving electron‐rich Fischer carbene species are largely underdeveloped and remain a big challenge. Here, a direct coupling reaction of azoles and azine N‐oxides is reported with Fischer copper carbene… read more here.
Keywords: relay; photoinduced copper; carbene species; catalyzed cross ... See more keywords
Enantioselective Synthesis of 2,2,3-Trisubstituted Indolines via Bimetallic Relay Catalysis of α-Diazoketones with Enones.
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DOI: 10.1021/acs.orglett.8b01744
Abstract: An efficient asymmetric intramolecular trapping of ammonium ylides of α-diazoketones with enones to synthesize indoline derivatives was realized. A Rh(II)/chiral N,N'-dioxide-Sc(III) complex bimetallic relay catalytic system was established. A series of optically active 2,2,3-trisubstituted indolines… read more here.
Keywords: trisubstituted indolines; synthesis trisubstituted; bimetallic relay; diazoketones enones ... See more keywords