A Chiral Iron Disulfonate Catalyst for the Enantioselective Synthesis of 2-Amino-2'-hydroxy-1,1'-binaphthyls (NOBINs).
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13020
Abstract: A novel type of chiral redox disulfonate iron complex for asymmetric catalysis is reported. The [Fe((Ra)-BINSate)]+ (BINSate = 1,1'-binaphthalene-2,2'-disulfonate) complex effectively promotes the enantioselective oxidative cross-coupling between 2-naphthols (1) and 2-aminonaphthalene derivatives (2), affording optically… read more here.
Keywords: amino hydroxy; iron; binaphthyls nobins; disulfonate ... See more keywords