Asymmetric Cation‐Binding Catalysis
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DOI: 10.1002/cctc.201601441
Abstract: The employment of metal salts is quite limited in asymmetric catalysis, although it would provide an additional arsenal of safe and inexpensive reagents to create molecular functions with high optical purity. Cation chelation by polyethers… read more here.
Keywords: asymmetric cation; cation; binding catalysis; catalysis ... See more keywords
Reductive Etherification via Anion-Binding Catalysis.
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DOI: 10.1021/jacs.7b05832
Abstract: Reductive condensations of alcohols with aldehydes/ketones to generate ethers are catalyzed by a readily accessible thiourea organocatalyst that operates in combination with HCl. 1,1,3,3-tetramethyldisiloxane serves as a convenient reducing reagent. This strategy is applicable to… read more here.
Keywords: reductive etherification; etherification via; binding catalysis; via anion ... See more keywords
Structural and functional analysis of Oceanobacillus iheyensis macrodomain reveals a network of waters involved in substrate binding and catalysis
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DOI: 10.1098/rsob.160327
Abstract: Macrodomains are ubiquitous conserved domains that bind or transform ADP-ribose (ADPr) metabolites. In humans, they are involved in transcription, X-chromosome inactivation, neurodegeneration and modulating PARP1 signalling, making them potential targets for therapeutic agents. Unfortunately, some… read more here.
Keywords: binding catalysis; oceanobacillus iheyensis; substrate binding; catalysis ... See more keywords