Tunable Binding of Dinitrogen to a Series of Heterobimetallic Hydride Complexes
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DOI: 10.1021/acs.organomet.8b00340
Abstract: The reaction of [Ru(H)2(N2)2(PCy3)2] (1) with β-diketiminate stabilized hydrides of Al, Zn, and Mg generates a series of new heterobimetallic complexes with either H2 or N2 ligated to the ruthenium center. Changing the main-group fragment… read more here.
Keywords: heterobimetallic hydride; binding dinitrogen; series heterobimetallic; series ... See more keywords