Selective Binding and Isomerization of Oximes in a Self-Assembled Capsule.
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DOI: 10.1021/jacs.2c12907
Abstract: A series of straight-chain (C7-C13) alkyl-O-methyl aldoximes (R-C(H)═NOMe) were synthesized with various functional groups at the remote ends (alkenes, halogen, -COOH, and NH2). Their isomers about the C═N bond showed ∼60-40% E-Z-ratio in organic solutions.… read more here.
Keywords: isomerization; selective binding; capsule; binding isomerization ... See more keywords