Insight into the preferential N-binding versus O-binding of nitrosoarenes to ferrous and ferric heme centers.
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DOI: 10.1039/d0dt03604h
Abstract: Nitrosoarenes (ArNOs) are toxic metabolic intermediates that bind to heme proteins to inhibit their functions. Although much of their biological functions involve coordination to the Fe centers of hemes, the factors that determine N-binding or… read more here.
Keywords: ferrous ferric; preferential binding; heme centers; insight preferential ... See more keywords