Regulation of circular dichroism behavior and construction of tunable solid-state circularly polarized luminescence based on BINOL derivatives
Sign Up to like & getrecommendations! Published in 2019 at "Materials Chemistry Frontiers"
DOI: 10.1039/c9qm00292h
Abstract: Circular dichroism behavior was regulated by controlling the molecular conformation of BINOL derivatives, and tunable solid-state circularly polarized luminescence was achieved. read more here.
Keywords: binol derivatives; circular dichroism; dichroism behavior; state circularly ... See more keywords
Rh(iii)-Catalyzed one-pot three-component cyclization reaction: rapid selective synthesis of monohydroxy polycyclic BINOL derivatives
Sign Up to like & getrecommendations! Published in 2021 at "Organic Chemistry Frontiers"
DOI: 10.1039/d1qo00779c
Abstract: A Rh(iii)-catalyzed three-component C–H bond functionalization protocol has been successfully applied to access complex polycyclic BINOL derivatives in which the formation of intermediate amides occurred in situ from aldehydes and amines. read more here.
Keywords: binol derivatives; polycyclic binol; three component; iii catalyzed ... See more keywords
Atroposelective synthesis of sterically hindered stereochemically complex BINOL derivatives via central-to-axial chirality induction
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DOI: 10.1039/d5sc05212b
Abstract: A sequential strategy is proposed for the atroposelective construction of new families of sterically hindered BINOL derivatives bearing multiple stereogenic elements and featuring up to four stereogenic centers. The sequence begins with an organocatalyzed regio-… read more here.
Keywords: sterically hindered; central axial; binol derivatives; chirality ... See more keywords
Advances in the Asymmetric Synthesis of BINOL Derivatives
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DOI: 10.3390/molecules28010012
Abstract: BINOL derivatives have shown relevant biological activities and are important chiral ligands and catalysts. Due to these properties, their asymmetric synthesis has attracted the interest of the scientific community. In this work, we present an… read more here.
Keywords: binol derivatives; asymmetric synthesis; advances asymmetric; synthesis binol ... See more keywords