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   Articles with "binuclear complexes" as a keyword



Oxy-functionalization of olefins with neat and heterogenized binuclear V(IV)O and Fe(II) complexes: Effect of steric hindrance on product selectivity and output in homogeneous and heterogeneous phase

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recommendations! Published in 2019 at "Molecular Catalysis"

DOI: 10.1016/j.mcat.2019.110424

Abstract: Abstract Neat {[VO(sal2bz)]2; [Fe(sal2bz)(H2O)2]2·2H2O} and zeolite-Y immobilized {[VO(sal2bz)]2-Y; [Fe(sal2bz)(H2O)2]2-Y} binuclear complexes have been prepared and characterized by spectroscopic techniques (IR, UV–vis), elemental analyses (CHN, ICP-OES), thermal study (TGA), scanning electron micrograph (SEM), adsorption study (BET)… read more here.

Keywords: steric hindrance; oxidation; binuclear complexes; cyclohexene ... See more keywords

Synthesis, characterization and molecular modeling of binuclear Pd(II) and Ir(IV) complexes with bis [4-hydroxy-6-methyl-3-{(1E)-N-[2-(ethylamino)ethyl]ethanimidoyl}-2H-pyran-2-one]: Application to detection of glucose

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recommendations! Published in 2018 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2018.05.075

Abstract: Abstract Two binuclear Pd (II) and Ir(IV) complexes with new bis [4-hydroxy-6-methyl-3-{(1E)-N-[2-(ethylamino) ethyl] ethanimidoyl}-2H-pyran-2-one] ligand (Schiff base: L) have been prepared and characterized by elemental analysis, ESI-MS, conductivity, NMR (1H NMR, 13C NMR, COSY-NMR, HMBC-NMR… read more here.

Keywords: ethylamino ethyl; hydroxy methyl; geometry; methyl ethylamino ... See more keywords

Binuclear Co(II) complexes with macrocycle and carboxylato ligands: structure, cytotoxicity and thermal behavior

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recommendations! Published in 2021 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2021.130133

Abstract: Abstract In vitro cytotoxic evaluation, formation constants and thermal stability of four mixed-ligand Co(II) complexes with tpmc = N,N',N",N'"-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane and carboxylate/dicarboxylate co-ligands of formulas [Co2(benz)2tpmc](ClO4)2•3H2O (1), benz– = benzoate anion; [Co2(L)tpmc](ClO4)2•nH2O, L = pht2– (phthalate dianion), n=2 (2), L = ipht2–… read more here.

Keywords: binuclear complexes; structure; thermal behavior; tpmc ligand ... See more keywords

Half-Lantern Binuclear Pt(II) Complexes with Heteroleptic Cyclometalated 2-Phenylpyridine Ligands: Synthesis, Metal-Induced Planar Chirality, Chirality Self-Sorting, and Chiroptical Properties.

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recommendations! Published in 2025 at "Organic letters"

DOI: 10.1021/acs.orglett.5c01835

Abstract: Half-lantern binuclear Pt(II) complexes bearing two heteroleptic cyclometalated 2-phenylpyridine ligands were synthesized and characterized for the first time. Heteroleptic cyclometalation is favorable for achieving an asymmetric charge distribution and for tuning optical properties. The maximum… read more here.

Keywords: binuclear complexes; heteroleptic cyclometalated; lantern binuclear; half lantern ... See more keywords