A hydroperoxo-rebound mechanism of alkane oxidation with hydrogen peroxide catalyzed by binuclear manganese(IV) complex in the presence of an acid with involvement of atmospheric dioxygen
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2016.04.035
Abstract: Abstract The binuclear manganese(IV) complex [Mn 2 L 2 O 3 ][PF 6 ] 2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane) (compound 1 ) catalyzes very efficiently the oxygenation of alkanes with H 2 O 2 only if a carboxylic… read more here.
Keywords: oxidation; alkane; hydrogen peroxide; manganese complex ... See more keywords
Zero-dimensional hybrid binuclear manganese chloride with thermally stable yellow emission.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01522f
Abstract: Photoluminescence (PL) thermal quenching of hybrid metal halides blocks their applications. Herein, a novel type of 0D hybrid metal halide, [Pb(C12H24O6)Cl]2[Mn2Cl6], with broad yellow emission and near-unity PL quantum yield is reported. Importantly, it preserves… read more here.
Keywords: binuclear manganese; dimensional hybrid; emission; yellow emission ... See more keywords