Reductive activation of O2 by a bioinspired Fe complex for catalytic epoxidation reactions.
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DOI: 10.1039/c7cc00933j
Abstract: Aerobic epoxidation of olefins catalyzed by iron complexes without the use of a sacrificial coreductant is unknown. We report the reductive activation of O2 by a bioinspired [(bTAML)FeIII(H2O)]- (1) complex to catalyze the epoxidation of… read more here.
Keywords: activation bioinspired; reductive activation; bioinspired complex; epoxidation ... See more keywords