Bioinspired Co(II) and Zn(II) complexes with an imidazole derived tripodal ligand. Structural models for astacins and MnSOD
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.01.059
Abstract: Abstract The syntheses of a new imidazole based tripodal ligand, namely N , N- bis(2-ethyl-4-methyl-imidazo-5-yl-methylen)-glycine (HemiGly) and its complexes with Co(II) and Zn(II) are described. HemiGly was prepared by a modification of the Mannich reaction… read more here.
Keywords: derived tripodal; imidazole derived; tripodal ligand; bioinspired complexes ... See more keywords
Bioinspired Di-Fe Complexes: Correlating Structure and Proton Transfer over Four Oxidation States.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12888
Abstract: Metalloproteins with active sites containing di-Fe cores exhibit diverse chemical reactivity that is linked to the precise transfer of protons and electrons which directly involve the di-Fe units. The redox conversions are commonly corroborated by… read more here.
Keywords: oxidation; complexes correlating; proton transfer; correlating structure ... See more keywords