Bioinspired synthesis of protein-posnjakite organic-inorganic nanobiohybrid for biosensing applications.
Sign Up to like & getrecommendations! Published in 2021 at "Analytica chimica acta"
DOI: 10.1016/j.aca.2020.11.026
Abstract: This study demonstrated a facile, green and bioinspired approach to synthesize protein-posnjakite nanobiohybrid with rod-assembled hollow shuttle-like structure. Through the one-pot mild coprecipitation process, the inorganic mineral posnjakite (Cu4(SO4) (OH)6·H2O) served as a nanocarrier to… read more here.
Keywords: protein; synthesis protein; bioinspired synthesis; protein posnjakite ... See more keywords
A Unifying Bioinspired Synthesis of (−)-Asperaculin A and (−)-Penifulvin D
Sign Up to like & getrecommendations! Published in 2021 at "Organic Letters"
DOI: 10.1021/acs.orglett.1c00955
Abstract: The first syntheses of the isomeric dioxafenestrene natural products (−)-asperaculin A and (−)-penifulvin D are reported. Each target is formed selectively by choice of oxidant in a final divergent bioinspired Baeyer–Villiger (BV) reaction. Density functional… read more here.
Keywords: bioinspired synthesis; penifulvin; synthesis asperaculin; unifying bioinspired ... See more keywords
Bioinspired Synthesis of Nortriterpenoid Propindilactone G.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c00363
Abstract: A concise bioinspired synthesis of Schisandra nortriterpenoid propindilactone G has been accomplished from a readily accessible steroidal lactone. Key transformations include a Breslow remote functionalization, a Suárez remote radical functionalization, a ring expansion enabled by… read more here.
Keywords: bioinspired synthesis; nortriterpenoid propindilactone; propindilactone; synthesis nortriterpenoid ... See more keywords
Bioinspired synthesis of pentalene-based chromophores from an oligoketone chain.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc02379d
Abstract: We report a bioinspired synthesis of 2,5-dihydropentalene-based chromophores from an aliphatic oligoketone bearing 1,3- and 1,4-diketone subunits. Unlike the natural polyketone sequence, fused five-membered rings were formed via an intramolecular aldol condensation. A subsequent Knoevenagel… read more here.
Keywords: pentalene based; chain; bioinspired synthesis; synthesis pentalene ... See more keywords