Biomimetic Synthesis of the CDE Ring Moiety of Physalins, Complex 13,14-Secosteroids.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.0c04198
Abstract: Physalins are a structurally complex family of 13,14-secosteroids isolated from the genus Physalis. We disclose a two-step construction of the CDE ring moiety of the physalins from a steroidal compound bearing 14-OH, 18-COOMe, and 17,… read more here.
Keywords: cde ring; ring moiety; biomimetic synthesis; moiety physalins ... See more keywords
Biomimetic Synthesis of Cyanogramides B and C.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00510
Abstract: Marinacarboline E and cyanogramides B and C from the marine-derived bacterium Actinoalloteichus cyanogriseus have been synthesized. The key step is the Baeyer-Villiger oxidation of marinacarboline E to a ketene aminal via O → N acetyl… read more here.
Keywords: synthesis cyanogramides; biomimetic synthesis;
Biomimetic Synthesis of Chejuenolides A–C by a Cryptic Lactone-Based Macrocyclization: Stereochemical Implications in Biosynthesis
Sign Up to like & getrecommendations! Published in 2023 at "ACS Central Science"
DOI: 10.1021/acscentsci.2c01096
Abstract: A hypothetical Mannich macrocyclization in the biosynthesis of chejuenolides A–C served as the basis for the synthetic design herein. Using a lactone-based linear precursor constructed via a tactic sequence of aldol–Julia–aldol reactions on a gram… read more here.
Keywords: synthesis chejuenolides; lactone based; macrocyclization; biomimetic synthesis ... See more keywords
Biomimetic synthesis of cerium oxide nanosquares on RGO and their enhanced photocatalytic activities.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c6dt03375j
Abstract: Water splitting based on heterogeneous photocatalytic nanomaterials is an attractive approach for generating hydrogen as a clean chemical fuel from solar energy. However, the high defect-induced recombination rate of photoexcited electron-hole pairs and poor photostability… read more here.
Keywords: synthesis cerium; biomimetic synthesis; cerium oxide; nanosquares rgo ... See more keywords
Biomimetic synthesis of nudicaulins I and II, yellow pigments from the Iceland poppy Papaver nudicaule.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc07943b
Abstract: Indole and the anthocyanin orientalin proceed through a unique cascade sequence that leads to nudicaulins I and II in 92% yield. This biomimetic synthesis confirms the biosynthesis proposal for these structurally unprecedented flavoalkaloids that play… read more here.
Keywords: synthesis nudicaulins; biomimetic synthesis; iceland poppy; nudicaulins yellow ... See more keywords
Cationic cyclization reactions with alkyne terminating groups: a useful tool in biomimetic synthesis.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc05826f
Abstract: Cyclization reactions through cationic intermediates have become a highly valuable tool in organic synthesis. The use of alkynes as the terminating group in this type of cationic process offers wide synthetic possibilities because this group… read more here.
Keywords: cyclization reactions; cationic cyclization; cyclization; biomimetic synthesis ... See more keywords
Biomimetic synthesis of a novel O2-regeneration nanosystem for enhanced starvation/chemo-therapy
Sign Up to like & getrecommendations! Published in 2021 at "Nanotechnology"
DOI: 10.1088/1361-6528/ac2843
Abstract: Glucose oxidase-mediated starvation therapy that effectively cuts off energy supply holds great promise in cancer treatment. However, high glutathione (GSH) contents and anoxic conditions severely reduce therapy efficiency and cannot fully kill cancer cells. Herein,… read more here.
Keywords: biomimetic synthesis; starvation therapy; starvation; cancer ... See more keywords
Peptide Nanosheet-Inspired Biomimetic Synthesis of CuS Nanoparticles on Ti3C2 Nanosheets for Electrochemical Biosensing of Hydrogen Peroxide
Sign Up to like & getrecommendations! Published in 2022 at "Biosensors"
DOI: 10.3390/bios13010014
Abstract: Hydrogen peroxide (H2O2) is one of the intermediates or final products of biological metabolism and participates in many important biological processes of life activities. The detection of H2O2 is of great significance in clinical disease… read more here.
Keywords: hydrogen peroxide; synthesis; biomimetic synthesis; h2o2 ... See more keywords
Biomimetic Organic-Inorganic Hybrid Membranes for Removal of Fluoride Ions
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma15103457
Abstract: Carbon nanofibers (CaNFs) exhibit promising applications in the fields of environmental science and nanotechnology, and self-assembled peptide nanofibers (PNFs) are useful for the biomimetic synthesis of organic-inorganic hybrid nanomaterials and the fabrication of functional hybrid… read more here.
Keywords: membranes removal; inorganic hybrid; hybrid membranes; biomimetic synthesis ... See more keywords
Biomimetic Synthesis of PANI/Graphitic Oxidized Carbon Nitride for Supercapacitor Applications
Sign Up to like & getrecommendations! Published in 2022 at "Polymers"
DOI: 10.3390/polym14183913
Abstract: Polyaniline (PANI) composites have gained momentum as supercapacitive materials due to their high energy density and power density. However, some drawbacks in their performance remain, such as the low stability after hundreds of charge-discharge cycles… read more here.
Keywords: pani; carbon; graphitic oxidized; biomimetic synthesis ... See more keywords