Menaquinone Biosynthesis: New Strategies to Trap Radical Intermediates in the MqnE-Catalyzed Reaction.
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DOI: 10.1021/acs.biochem.1c00181
Abstract: Aminofutalosine synthase (MqnE) is a radical SAM enzyme that catalyzes the conversion of 3-((1-carboxyvinyl)oxy)benzoic acid to aminofutalosine during the futalosine-dependent menaquinone biosynthesis. In this Communication, we report the trapping of a radical intermediate in the… read more here.
Keywords: catalyzed reaction; menaquinone biosynthesis; biosynthesis new; mqne catalyzed ... See more keywords