An Unexpected Access to Phospholene Fused β-Phosphinolactams by the Reaction of α-C2-Bridged Biphospholes and Nitrones.
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DOI: 10.1021/acs.orglett.4c03062
Abstract: An efficient and practical method for the preparation of the phospholene fused β-phosphinolactam skeleton from α-C2-bridged biphospholes and nitrones is described. The dissociation of biphospholes generates transient 1-phosphafulvenes, followed by oxidation with nitrones to give… read more here.
Keywords: phospholene fused; access phospholene; biphospholes nitrones; unexpected access ... See more keywords