Interligand C-C Coupling between α-Methyl N-Heterocycles and bipy or phen at Rhenium Tricarbonyl Complexes.
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DOI: 10.1021/acs.inorgchem.7b00078
Abstract: Intramolecular C-C coupling between N-bonded 1,2-dimethylimidazole, 2-methyloxazoline, or 2-methylpyridine and either 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) ligands results from α-methyl group deprotonation in the coordination sphere of Re(CO)3 fragments. The nucleophilic CH2 group generated by… read more here.
Keywords: bipy phen; phen rhenium; interligand coupling; coupling methyl ... See more keywords
New binuclear copper(II) complexes [Cu2(L)4(μ-CO3)][B12H12] (L = bipy, phen): Synthesis, structure, and magnetic properties
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DOI: 10.1134/s0012500817060015
Abstract: The processes taking place in the CuI/L/solv system (L = bipy, phen) in the presence of the [B12H12]2– anion, which exhibited the lowest reducing ability among the [BnHn]2– cluster anions (n = 6, 10, 12),… read more here.
Keywords: bipy phen; co3 b12h12; copper; b12h12 ... See more keywords