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Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt02978e
Abstract: The oxidant diphenyldiselenide reacts with MIIMe2(bipy) (bipy = 2,2'-bipyridine) to form a pre-equilibrium involving weak adducts, from which [MMe2(bipy)]2·Ph2Se2 undergoes rate-limiting dissociation of phenylselenide preceded by the oxidative addition step to obtain [Me2(bipy)M-MMe2(bipy)(SePh)]+. Coordination of…
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Keywords:
bipy seph;
metal;
bipy;
mme2 bipy ... See more keywords