Enantiopure trigonal bipyramidal coordination cages templated by in situ self-organized D2h-symmetric anions
Sign Up to like & getrecommendations! Published in 2024 at "Nature Communications"
DOI: 10.1038/s41467-024-49964-w
Abstract: The control of a molecule’s geometry, chirality, and physical properties has long been a challenging pursuit. Our study introduces a dependable method for assembling D3-symmetric trigonal bipyramidal coordination cages. Specifically, D2h-symmetric anions, like oxalate and… read more here.
Keywords: bipyramidal coordination; trigonal bipyramidal; bipyramidal; coordination cages ... See more keywords
A new air- and moisture-stable pentagonal-bipyramidal DyIII single-ion magnet based on the HMPA ligand.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt03565b
Abstract: Based on the HMPA ligand, a new air- and moisture-stable pentagonal-bipyramidal DyIII single-ion magnet [Dy(HMPA)2(H2O)5]2·Br6·2HMPA·2H2O (1) was prepared and characterized. Single-crystal X-ray tests showed the two crystallographically independent DyIII ions located in a pentagonal-bipyramidal coordination… read more here.
Keywords: bipyramidal; based hmpa; dyiii; hmpa ligand ... See more keywords