Effective tuning of magnetic anisotropy in distorted pentagonal bipyramidal Ni(II) complexes via substitution of axial coligands.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02867k
Abstract: A series of Ni(II) complexes with pyridine-based macrocyclic ligand L (3,12,18-triaza-6,9-dioxabicyclo[12.3.1]octadeca-1(18),14,16-triene) with general formula [Ni(L)(X)2]0/2+ (X = Br- (1), I- (2), CH3CN (3), NCS- (4), imidazole (5)) was prepared and thoroughly investigated. X-ray molecular structures… read more here.
Keywords: magnetic anisotropy; pentagonal bipyramidal; bipyramidal complexes; axial coligands ... See more keywords
d+id chiral superconductivity in a triangular lattice from trigonal bipyramidal complexes
Sign Up to like & getrecommendations! Published in 2018 at "Physical Review B"
DOI: 10.1103/physrevb.97.165110
Abstract: We model the newly predicted high-$T_c$ superconducting candidates constructed by corner-shared trigonal bipyramidal complexes with an effective three-orbital tight-banding Hamiltonian and investigate the pairing symmetry of their superconducting states driven by electron-electron interactions. Our combined… read more here.
Keywords: chiral superconductivity; superconductivity triangular; trigonal bipyramidal; bipyramidal complexes ... See more keywords