Concomitant dimorphism in poly[di-μ-azido-(5,5'-dimethyl-2,2'-bipyridine)iron(II)].
Sign Up to like & getrecommendations! Published in 2022 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229622006908
Abstract: The title metal-organic polymer, catena-poly[[(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')iron(II)]-di-μ-azido-κ2N1:N3-[(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')iron(II)]-di-μ-azido-κ2N1:N1], [Fe(N3)2(C12H12N2)]n, features alternating μ-1,1 (end-on mode of coordination) and μ-1,3 (end-to-end mode of coordination) double azide bridges, forming chains running in the [100] direction. The octahedral coordination geometry around the… read more here.
Keywords: dimethyl bipyridine; azido; bipyridine iron;
Multi-Week Cycling of a Nonaqueous Flow Battery Using Tris-Bipyridine Iron (II) Triflate without Additional Supporting Electrolyte
Sign Up to like & getrecommendations! Published in 2023 at "Journal of The Electrochemical Society"
DOI: 10.1149/1945-7111/acd873
Abstract: Tris-bipyridine iron (II) triflate was synthesized and used as an active species to demonstrate a symmetric disproportionation redox-flow-battery chemistry that works without a supporting electrolyte. Solutions of this coordination complex salt (0.1 M in acetonitrile),… read more here.
Keywords: iron triflate; flow battery; bipyridine iron; supporting electrolyte ... See more keywords