Reduction of Dinitrogen via 2,3'-Bipyridine-Mediated Tetraboration.
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DOI: 10.1021/jacs.0c00409
Abstract: A new molecular system for nitrogen reduction, involving a 2,3'-bipyridine-anchored, end-on-bridging dinitrogen complex of the Me2B-BMe2 intermediate (4), has been explored by theoretical methods. The 2,3'-bipyridine-mediated cleavage of the Bsp3-Bsp3 bond in 4 may lead… read more here.
Keywords: dinitrogen; bipyridine; dinitrogen via; bipyridine mediated ... See more keywords