Acetylene storage performance of [Ni(4,4'-bipyridine)2(NCS)2]n, a switching square lattice coordination network.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06638b
Abstract: We report that the previously reported square lattice coordination network [Ni(4,4'-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake… read more here.
Keywords: bipyridine ncs; acetylene storage; lattice coordination; square lattice ... See more keywords
Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,4'-bipyridine)2(NCS)2]n.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc06549e
Abstract: Switching coordination networks (CNs) featuring stepped sorption isotherms that are accompanied by phase changes offer promise for gas storage and separation applications. However, their responsiveness to different adsorbates remains largely understudied. Herein, we report the… read more here.
Keywords: topology; bipyridine ncs; coordination; phase ... See more keywords