Highly Robust Rhenium(I) Bipyridyl Complexes Containing Dipyrromethene-BF2 Chromophores for Visible Light-Driven CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202200337
Abstract: Here we report new rhenium bipyridyl complexes with dipyrromethene-BF 2 chromophores (A-ReBDP-CZ, A-ReBDP 2 , ReBDP-CZ and ReBDP 2 ) for highly efficient photocatalytic carbon dioxide (CO 2 ) reduction to carbon monoxide (CO). These… read more here.
Keywords: bipyridyl complexes; visible light; rhenium bipyridyl; bipyridyl ... See more keywords
Trans Influence and Substituent Effects on the HOMO-LUMO Energy Gap and Stokes Shift in Ru Mono-Diimine Derivatives.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of molecular structure"
DOI: 10.1016/j.molstruc.2019.06.005
Abstract: The ground (S0) and excited triplet (T1) electronic states and corresponding optical spectra of a series of cationic complexes [RuH(CO)L(PPh3)2]+ (L=2,2´-bipyridyl) (Rubpy), 4,4´-dicarboxylic-2,2´-bipyridyl (Rudcbpy), bis-4,4'-(N-methylamide)-2,2´-bipyridyl (Rudamidebpy), bis-4,4'-(methyl)-2,2´-bipyridyl (RudMebpy), [Ru(CO)2dcbpy(PPh3)2]2+ (Ru(2CO)dcbpy), and [Ru(H)2dcbpy(PPh3)2] (Ru(2H)dcbpy) have been… read more here.
Keywords: stokes shift; lumo energy; homo lumo; gap stokes ... See more keywords
Syntheses, Structures, and Properties of Coordination Polymers with 2,5-Dihydroxy-1,4-Benzoquinone and 4,4′-Bipyridyl Synthesized by In Situ Hydrolysis Method
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c07077
Abstract: The coordination polymers (CPs) with binary ligands, including 2,5-dihydroxy-1,4-benzoquinone (H2DHBQ) and 4,4′-bipyridyl (bpy), were synthesized using in situ hydrolysis of 2,5-dimethoxy-1,4-benzoquinone (DMBQ). Three kinds of CPs were obtained depending on the metal ions. For M… read more here.
Keywords: dihydroxy benzoquinone; situ hydrolysis; benzoquinone; bipyridyl ... See more keywords