Magnetic relaxation in unique nitronyl nitroxide biradical-Ln-Cu chains with Ln-bis(NIT)-Cu-bis(NIT)-Ln units.
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DOI: 10.1039/d3dt00752a
Abstract: Utilizing a nitronyl nitroxide biradical NITPhPybis [5-(4-pyridyl)-1,3-bis(1'-oxyl-3'-oxido-4',4',5',5'-tetramethyl-4,5-hydro-1H-imidazol-2-yl)-benzene], a new family of isomorphic 2p-3d-4f chains {[LnCu(hfac)5(NITPhPybis)]·CHCl3}n (hfac: hexafluoroacetylacetonate; LnIII: Gd 1; Dy 2; Ho 3; Tb 4) have been successfully produced. In complexes 1-4, the NITPhPybis… read more here.
Keywords: nitronyl nitroxide; nitroxide biradical; magnetic relaxation; nit bis ... See more keywords