Synthesis of a mononuclear magnesium bis(alkoxide) complex and its reactivity in the ring-opening copolymerization of cyclic anhydrides with epoxides.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04274a
Abstract: Synthesis of a new mononuclear magnesium complex with a bulky bis(alkoxide) ligand environment and its reactivity in ring-opening polymerization (ROP) and ring-opening copolymerization (ROCOP) are reported. Reaction of n-butyl-sec-butylmagnesium with two equivalents of HOR (HOR… read more here.
Keywords: ring opening; bis alkoxide; copolymerization; mononuclear magnesium ... See more keywords
Synthesis and structure of a new bulky bis(alkoxide) ligand on a terphenyl platform
Sign Up to like & getrecommendations! Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989021013438
Abstract: A new potentially chelating bulky bis(alkoxide) exhibits anti conformation of the O-atom donors in the solid state and does not form transition-metal complexes. read more here.
Keywords: bulky bis; synthesis structure; bis alkoxide; structure new ... See more keywords