Copper-Catalyzed Coupling of Alkyl Vicinal Bis(boronic Esters) to an Array of Electrophiles.
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DOI: 10.1021/jacs.2c02817
Abstract: A neighboring boronate group in the substrate provides a dramatic rate acceleration in transmetalation to copper and thereby enables organoboronic esters to participate in unprecedented site-selective cross-couplings. This cross-coupling operates under practical experimental conditions and… read more here.
Keywords: bis boronic; boronic esters; vicinal bis; catalyzed coupling ... See more keywords