Synthesis and Properties of Bis-corannulenes.
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DOI: 10.1021/acs.orglett.1c00146
Abstract: Corannulenecarbaldehyde and corannulenylmethyl triphenylphosphonium bromide are combined through the Wittig olefination reaction to furnish dicorannulenylethene with 70% yield. A subsequent oxidative photocyclization leads to annulation of the corannulene nuclei to produce a C42H18 nanographene structure… read more here.
Keywords: properties bis; bis corannulenes; yield; synthesis properties ... See more keywords