Articles with "bis cyclometalated" as a keyword



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Formazanate Complexes of Bis-Cyclometalated Iridium.

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Published in 2019 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.9b01657

Abstract: In this work we describe a series of bis-cyclometalated iridium(III) formazanate complexes, expanding the coordination chemistry of the redox-active formazanate class to iridium. A total of 18 new complexes are described, varying the substituent pattern… read more here.

Keywords: formazanate complexes; formazanate; chemistry; spectroscopy ... See more keywords
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New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand: Electrochemical and Photophysical Insights

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Published in 2022 at "International Journal of Molecular Sciences"

DOI: 10.3390/ijms23147606

Abstract: An efficient synthetic access to new cationic porphyrin-bipyridine iridium(III) bis-cyclometalated complexes was developed. These porphyrins bearing arylbipyridine moieties at β-pyrrolic positions coordinated with iridium(III), and the corresponding Zn(II) porphyrin complexes were spectroscopically, electrochemically, and electronically… read more here.

Keywords: bis cyclometalated; new bis; iridium iii; iii complexes ... See more keywords