Synthesis and catalytic reactivity in Friedel–Crafts acylations of monobridged bis(cyclopentadienyl)molybdenum(I) carbonyl complexes
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.03.021
Abstract: Abstract When the monobridged biscyclopentadienes (C5H5)R(C5H5) [R = C(CH3)2 (1), Si(CH3)2 (2), C(CH2)5 (3)] reacted with Mo(CO)6 in refluxing xylene, the corresponding complexes [(η5-C5H4)2R][Mo(CO)3]2 [R = C(CH3)2 (4), Si(CH3)2 (5), C(CH2)5 (6)] were obtained. These complexes were separated by… read more here.
Keywords: molybdenum carbonyl; cyclopentadienyl molybdenum; bis cyclopentadienyl; carbonyl complexes ... See more keywords
Synthesis and Reduction of Heteroleptic Bis(cyclopentadienyl) Uranium(III) Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00322
Abstract: Heteroleptic U(III) complexes supported by bis(cyclopentadienyl) frameworks have been synthesized to examine their suitability as precursors to U(II) complexes. The newly synthesized (C5Me5)2U(OC6H2tBu2-2,6-Me-4), (C5Me5)2U(OC6H2Ad2-2,6-tBu-4) (Ad = 1-adamantyl), (C5Me5)2U(C5H5), and (C5Me5)2U(C5Me4H) are compared with (C5Me5)2U[N(SiMe3)2], (C5Me5)2U[CH(SiMe3)2],… read more here.
Keywords: c5me5; bis cyclopentadienyl; c5me5 sime3; iii complexes ... See more keywords
Bis(cyclopentadienyl)nickel(II) μ-Thiolato Complexes as Proton Reduction Electrocatalysts.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01507
Abstract: Thiolato-bridged cyclopentadienylnickel dimeric complexes have been prepared and found to be efficient and robust proton reduction electrocatalysts using acetic acid as the proton source. From cyclic voltammetry studies, moderate overpotentials of around 0.6 V and… read more here.
Keywords: reduction; bis cyclopentadienyl; proton reduction; thiolato ... See more keywords
Orbital control over the metal vs. ligand reduction in a series of neutral and cationic bis(cyclopentadienyl) Ti(IV) complexes
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c7nj03746e
Abstract: Quantum chemistry calculations showed that the first reduction, as experimentally observed by cyclic voltammetry for a series of neutral and cationic functionalised bis(cyclopentadienyl) titanium(IV) derivatives, is metal based, involving the chemically and electrochemically reversible TiIV/TiIII… read more here.
Keywords: reduction; bis cyclopentadienyl; chemistry; neutral cationic ... See more keywords
The Cytotoxic Activity of Diiron Bis-Cyclopentadienyl Complexes with Bridging C3-Ligands
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DOI: 10.3390/app11104351
Abstract: Diiron bis-cyclopentadienyl bis-carbonyl cationic complexes with a bridging vinyliminium ligand, [Fe2Cp2(CO)(μ-CO){μ-η1:η3-C3(R′)C2HC1NMe(R″)}]CF3SO3 (R = Xyl = 2,6-C6H3Me2, R′ = Ph, R″ = H, 2a; R = Xyl, R′ = R″ = Me, 2b; R = R′… read more here.
Keywords: diiron; bis cyclopentadienyl; activity; cell ... See more keywords