A Single-Molecule Magnet Tetranuclear [Mn3IIIMnIVO3Cl] Complex with Bis(diisopropylphosphinyl)imide Ligands
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Cluster Science"
DOI: 10.1007/s10876-018-1442-y
Abstract: Treatment of Mn(OAc)2·4H2O with 3 equiv. HN(iPr2PO)2 in the presence of nBu4NCl in acetonitrile resulted in isolation of a tetranuclear {Mn3IIIMnIV} complex [Mn4(μ3-O)3(μ3-Cl)(μ-OAc)3{N(iPr2PO)2}3]·0.5C6H14 (1·0.5C6H14), and a dinuclear {MnIIMnIII} complex [Mn2{N(iPr2PO)2}{μ2,η3-(iPrPO2)NH(iPr2PO)}2{η2-(iPrPO2)NH(iPr2PO)}2]·0.25AcOH (2·0.25AcOH) with bis(diisopropylphosphinyl)imide ligands. The… read more here.
Keywords: diisopropylphosphinyl imide; molecule; bis diisopropylphosphinyl; single molecule ... See more keywords